Absorptions features near 28 cm−1 are assigned to ν1 and ν4 modes of CH3S, respectively, and those near 29 cm−1 are tentatively assigned as combination transitions 315161(e) and 315161(a), respectively, from the ground vibrational state.► We applied the (1 + 1) IR-VUV photoionization method to obtain the IR spectrum of the CH3S radical in the range 2780–3270 cm−1. The IR spectrum of CH3S was obtained in the range 2790–3270 cm−1. Photolysis of CH3SH produced CH3S radicals that were ionized with (1 + 1) IR-VUV photoionization and detected with the time-of-flight technique. Hibbeler currently teaches at the University of Louisiana-Lafayette.We present a detailed spectral study of the atmospherically important methylthio (CH3S) radical demonstrating the advantage of IR-VUV photoionization for vibrational spectroscopy of free radicals due to its mass selectivity. He has taught at the University of Illinois-Urbana, Youngstown State University, Illinois Institute of Technology, and Union College. He has practiced engineering in Ohio, New York, and Louisiana. Hibbeler's professional experience includes postdoctoral work in reactor safety and analysis at Argonne National Laboratory, and structural work at Chicago Bridge and Iron, Sargent and Lundy, Tucson. in Theoretical and Applied Mechanics from Northwestern University. in Civil Engineering (major in structures) and an M.S. "Russ Hibbeler "graduated from the University of Illinois-Urbana with a B.S. He has practiced engineering in Ohio, New York, and.
|
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |